Publications

2024
  1. Wu, S.; Micouin L.; Benedetti E. “Practical access to planar chiral benzophenones derived from [2.2]paracyclophane” Synlett 2024, Accepted Manuscript, DOI: 10.1055/a-2284-4984.
  2. Flichot, H.; Sickinger, A.; Brom, J.; Lefeuvre, B.; Dorcet, V.; Guizouarn, T.; Cador, O.; Le Guennic, B.; Micouin, L.; Maury, O.; Benedetti, E.; Pointillart, F. “Magneto-structural correlation in lanthanide luminescent [2.2]Paracyclophane-based Single-Molecule Magnets“  Dalton Trans. 2024, Accepted Manuscript, DOI:10.1039/D4DT00536H.
  3. Wu, S.; Felder, S.; Brom, J.; Pointillart, F.; Maury, O.; Micouin L.; Benedetti E. [2.2]Paracyclophanes: from selective functionalization to optical properties Adv. Optical. Mater. 2024, Accepted Manuscript
  4. T. Zhao, E. Sachon, L. Micouin, R. Piccardi “α-Silylated Diazoalkynes: New Tools for Bioconjugation of Proteins” 2024, 30, e202302807.
    DOI: 10.1002/chem.202302807
  5. L. Micouin, R. Piccardi, Organoaluminum Reagents, in Reference Module in Chemistry, Molecular Sciences and Chemical Engineering, Elsevier, 2024, ISBN 9780124095472, DOI: 10.1016/B978-0-323-96025-0.00041-7.
2023
  1. Brom, J.; Maruani, A.; Turcaud, S.; Lajnef, S.; Peyrot, F.; Micouin, L.; Benedetti, E. “[2.2]Paracyclophane-based coumarins: effective organo-photocatalysts for light-induced desulfonylation processes” Org. Biomol. Chem. 2023, just accepted. DOI: 10.1039/D3OB01711G (Preprint ChemRxiv – DOI: 10.26434/chemrxiv-2023-n4ds3).
  2. Brom, J.; Maruani, A.; Micouin, L.; Benedetti, E. “Light-driven reductive cleavage of sulfonamides promoted by thiourea organophotosensitizers”. J. Org. Chem. 2023,  88, 5923. DOI: 10.1021/acs.joc.3c00296 (Preprint ChemRxiv – DOI: 10.26434/chemrxiv-2022-jvdqw)
  3. Fleurisson, C.; Graidia, N.; Foricher, Y.; Benedetti, E.; Micouin, L.;  “Intramolecular Buchwald-Hartwig N-Arylation of Bicyclic Hydrazines: Practical Access to Spiro[indoline-2,3′-piperidines]”  Org. Biomol. Chem. 2023, 21, 3542. DOI: 10.1039/D3OB00406F (Preprint ChemRxiv – DOI: 10.26434/chemrxiv-2022-rqsqc)
  4. Felder, S.; Delcourt, M.-L.; Rodríguez, R.; Favereau, L.; Jeanne Crassous, J.; Micouin, L.; Benedetti, E. “Compact CPL emitters based on a [2.2]paracyclophane scaffold: recent developments and future perspectives”, J. Mater. Chem. C 2023, 11, 2053 DOI: https://doi.org/10.1039/D2TC04885J
2022
  1. S. Felder, C. Sagné, E. Benedetti, L. Micouin “Small-Molecule 3D Ligand for RNA Recognition: Tuning Selectivity through Scaffold Hopping” ACS Chemical Biology, 2022, 17, 3069. DOI: https://doi.org/10.1021/acschembio.2c00171
  2. S. Felder, M.-L. Delcourt, M.H.E. Bousquet, D.  Jacquemin, R. Rodríguez, L. Favereau, J. Crassous, L. Micouin, E. Benedetti “Planar chiral analogues of PRODAN based on a [2.2]paracyclophane scaffold: Synthesis and photophysical studies”. J. Org. Chem. 2022, 87, 147-158 DOI: https://doi.org/10.1021/acs.joc.1c02071
  3. Bicyclic 5-5 systems with one ring junction nitrogen atom: Two extra heteroatoms 2:0 Benedetti, E.; Micouin, L. Reference Collection in Chemistry, Molecular Science and Chemical Engineering Wiley, 2022. Volume 11, pp 145-173. DOI:10.1016/B978-0-12-409547-2.14935-2 
2021
  1. S. Wu, L.A. Galan, M. Roux, F. Riobe, B. Le Guennic, Y. Guyot, T. Le Bahers, L. Micouin, O. Maury, E. Benedetti “Tuning the excited state properties of [2.2]paracyclophane-based antennas to ensure efficient sensitization of lanthanide ions or singlet oxygen generation” Inorg. Chem. 2021, 60, 16194−16203. DOI: https://doi.org/10.1021/acs.inorgchem.1c01986
  2. S. Felder, S. Wu, J. Brom, L. Micouin, E. Benedetti,  “Enantiopure planar chiral [2.2]paracyclophanes: Synthesis and applications in asymmetric organocatalysis” Chirality, 2021, 33, 506-527 DOI: https://doi.org/10.1002/chir.23335
  3. S. Felder, L. Micouin, E. Benedetti “Para‐functionalization of N‐substituted 4‐amino[2.2]paracyclophanes by regioselective formylation” Eur. J. Org. Chem., 2021, 4015-4018. DOI: https://doi.org/10.1002/ejoc.202100288
  4. C. Fleurisson, E. Benedetti, L. Micouin Cyclic cis-1,3-Diamines Derived from Bicyclic Hydrazines: Synthesis and Applications Synlett 2021, 31, 858-874. DOI: 10.1055/s-0040-1707324
2020
  1. C. Aubry, P. Clerici, C. Gerbaud, L. Micouin, J.-L. Pernodet, S. Lautru, “Revised structure of Anthelvencine A and characterization of the Anthelvencin Biosynthetic gene cluster”.  ACS Chem Biol. 2020, 15, 945-951. https://doi.org/10.1021/acschembio.9b00960
  2. C. Fleurisson, E. Benedetti, L. Micouin” Cyclic cis-1,3-Diamines Derived from Bicyclic Hydrazines: Synthesis and Applications” Synlett published online. DOI: 10.1055/s-0040-1707324
  3. X. Chen, P. Coric, V. Larue, S. Turcaud, X. Wang, S. Nonin-Lecomte, S. Bouaziz “The HIV-1 maturation inhibitor, EP39, interferes with the dynamic helix-coil equilibrium of the CA-SP1 junction of Gag” Eur. J. Med. Chem., 2020, 204, 112634 DOI: https://doi.org/10.1016/j.ejmech.2020.112634
  4. Bicyclic 5-5 systems with one ring junction nitrogen atom: Two extra heteroatoms 2:0 Benedetti, E.; Micouin, L. Reference Collection in Chemistry, Molecular Science and Chemical Engineering Wiley, 2020. DOI:10.1016/B978-0-12-409547-2.14935-2 
2019
  1. M.-L.Delcourt, C. Reynaud, S. Turcaud, L. Favereau, J. Crassous, L. Micouin, E. Benedetti, 3D Coumarin Systems Based on [2.2]Paracyclophane: Synthesis, Spectroscopic Characterization, and Chiroptical Properties. J. Org. Chem. 2019, 84 , 888–899. https://doi.org/10.1021/acs.joc.8b02773.
  2. M.-L. Delcourt, S. Felder, S. Turcaud, C. H. Pollok, C. Merten, L. Micouin, E. Benedetti,  Highly Enantioselective Asymmetric Transfer Hydrogenation: A Practical and Scalable Method To Efficiently Access Planar Chiral [2.2]Paracyclophanes. J. Org. Chem. 2019, 84 , 5369–5382. https://doi.org/10.1021/acs.joc.9b00372
  3. R. Piccardi, S. Turcaud, E. Benedetti, L. Micouin, Synthesis and Reactivity of Mixed Dimethylalkynylaluminum Reagents. Synthesis, 2019, 51 , 97–106. https://doi.org/10.1055/s-0037-1610392 (Published as part of the 50 Years SYNTHESIS – Golden Anniversary Issue)
  4. T. Zhao, L. Micouin, R. Piccardi, Synthesis of organometallic compounds in Flow, Helv. Chim. Acta, 2019, accepted https://doi.org/10.1002/hlca.201900172 (Special Issue for the 60th anniversary of Pr. Philipe Reanud)
2018
  1. M.-L. Delcourt, S. Simon, E. Benedetti, L.Micouin, Highly Enantioselective Desymmetrization of Centrosymmetric pseudo-para-Diformyl[2.2]paracyclophane via Asymmetric Transfer Hydrogenation ACS Catalysis, 2018, 8, 6612-6616
  2. T. Zhao, R. Piccardi, L. Micouin. Rapid and Effective Synthesis of α-Acyloxy-α-alkynyltrimethylsilanes Org. Lett., 2018,20, 5015-5018
  3. A. Blond, S. Turcaud, T. Lecourt, L. Micouin Diastereoselective Ring Homologation of Bicyclic Hydrazines: Access to Cis-1,3-Diaminocyclohexitols. ACS OMEGA 2018, 3, 15302–15307. https://doi.org/10.1021/acsomega.8b02910.
2017
  1. E. Benedetti, M.-L. Delcourt, B. Gatin-Fraudet, S. Turcaud, L. Micouin, Synthesis and photophysical studies of through-space conjugated [2.2]paracyclophane-based naphthalene fluorophores RSC Advances, 2017, 7, 50472-50476.
  2. H. Guyon, F. Mavré, M. Catala, S. Turcaud, F. Brachet, B. Limoges, C. Tisné, L. Micouin Use of a redox probe for an electrochemical RNA–ligand binding assay in microliter droplets Chem. Commun., 2017, 53, 1140-1143
  3. A. Joosten, M. Boultadaki-Arapinis, V. Gandon, L. Micouin, T. Lecourt, Substitution of the Participating Group of Glycosyl Donors by a Halogen Atom: Influence on the Rearrangement of Transient Orthoesters Formed during Glycosylation Reactions J. Org. Chem. 2017, 82, 3291-3297
  4. P. Gordillo, P. Clerici, L. Micouin Modular access to N-substituted cis 5-amino-3-hydroxypiperidines J. Org. Chem. 2017, 82, 7689-7694.