Laboratoire de Chimie et Biochimie
Pharmacologiques et Toxicologiques (LCBPT)
CNRS UMR 8601
Université Paris Descartes
45 Rue des Saints Pères
75270 Paris Cedex 06
France

Farouk BERHAL

Assistant Professor

Laboratoire de Chimie et Biochimie pharmacologiques et toxicologiques (LCBPT) – CNRS UMR 8601
Université Paris Descartes
45 Rue des Saints Pères
75270 Paris Cedex 06
France

Curriculum Vitae

  • Sept. 2013- Asssitant Professor (CNU 32) – UMR 8601 LCBPT
    Development of new transition-metal-catalyzed domino processes.
  • 2012-2013 ATER, Pr. Guillaume Prestat – UMR 8601 LCBPT
    New strategies towards the synthesis of  of Liposidomycines analogs
  • 2010-2012 Post-doctoral associate (11 months) and ATER (12 months) Dr. Virginie Ratovelomanana-Vidal – Chimie ParisTech : UMR 7223
    Addition conjuguée d’acides boroniques / Hydrogénation asymétrique d’hétérocycles azotés.
  • 2009-2010 Post-doctoral associate (15 mois), Pr. Masakatsu Shibasaki
    Graduate School of Pharmaceutical Sciences, The University of Tokyo, Japon
    Total synthesis of  Mycestericines F et G.
  • 2005-2008 PhD Thesis, Dr. Jacques Royer
    Faculté des Sciences Pharmaceutiques et Biologiques – Université Paris Descartes : UMR 8638
    Asymmetric syntheis of cephalotoxine analogs and esters.

Publications

2024

Esteves, H.; Xavier, T.; Lajnef, S.; Peyrot, F.; Lefèvre, G.; Prestat, G.*; Berhal, F.* “Iron-Catalyzed Intramolecular C(sp3)-H Lactonization of Hydroxamate Derivatives Promoted by a 1,5-HAT.” ACS Catal. 2024, 14 (6), 4329–4339. https://doi.org/10.1021/acscatal.3c04900.

2023

Kirby, G.; Prestat, G.*; Berhal, F.* “Iron-Catalyzed Intermolecular Oxyamination of Terminal Alkenes Promoted by HFIP Using Hydroxylamine Derivatives.” J. Org. Chem. 2023, 88 (7), 4720–4729. https://doi.org/10.1021/acs.joc.3c00198

2022

da Cunha, M. F.; Pranke, I.; Sassi, A.; Schreiweis, C.; Moriceau, S.; Vidovic, D.; Hatton, A.; Carlon, M. S.; Creste, G.; Berhal, F.; Prestat, G.; Freund, R.; Odolczyk, N.; Jais, J. P.; Gravier-Pelletier, C.; Zielenkiewicz, P.; Jullien, V.; Hinzpeter, A.; Oury, F.; Edelman, A.; Sermet-Gaudelus, I. Systemic Bis-Phosphinic Acid Derivative Restores Chloride Transport in Cystic Fibrosis Mice. Sci Rep 2022, 12 (1), 6132. https://doi.org/10.1038/s41598-022-09678-9.

2021

Kirby, G.; Grimaud, L.; Vitale, M. R.; Prestat, G.; Berhal, F. Iron(II)-Catalyzed Intermolecular Aziridination of Alkenes Employing Hydroxylamine Derivatives as Clean Nitrene Sources. Green Chem. 2021, 23 (23), 9428–9432 doi: 10.1039/D1GC03495B

Bitam, S.; Elbahnsi, A.; Creste, G.; Pranke, I.; Chevalier, B.; Berhal, F.; Hoffmann, B.; Servel, N.; Tondelier, D.; Hatton, A.; Moquereau, C.; Faria Da Cunha, M.; Pastor, A.; Lepissier, A.; Hinzpeter, A.; Mornon, J.-P.; Prestat, G.; Edelman, A.; Callebaut, I.; Gravier-Pelletier, C.; Sermet-Gaudelus, I. New Insights into Structure and Function of Bis-Phosphinic Acid Derivatives and Implications for CFTR Modulation. Sci Rep 2021, 11 (1), 6842. https://doi.org/10.1038/s41598-021-83240-x.

Bardin, E.; Pastor, A.; Semeraro, M.; Golec, A.; Hayes, K.; Chevalier, B.; Berhal, F.; Prestat, G.; Hinzpeter, A.; Gravier-Pelletier, C.; Pranke, I.; Sermet-Gaudelus, I. Modulators of CFTR. Updates on Clinical Development and Future Directions. Eur. J. Med. Chem. 2021, 113195 doi.org/10.1016/j.ejmech.2021.113195

2020

Abi Fayssal, S.; Giungi, A.; Berhal, F.; Prestat, G. Iron-Catalyzed Intra-Intermolecular Aminoazidation of Alkenes. Org. Process Res. Dev. 202024, 695 10.1021/acs.oprd.9b00400.

2018
  • Manick, A.-D.; Aubert, S.; Yalcouye, B.; Prangé, T.; Berhal, F.; Prestat, G. Access to functionalized imidazolidin‐2‐one derivatives by iron‐catalyzed oxyamination of alkenes, Chem. Eur. J. 2018, 24, 11485-11492. 10.1002/chem.201802190
  • Manick, A.-D.; Berhal, F.; Prestat, G. Development of a One-Pot Four C−C Bond-Forming Sequence Based on Palladium/Ruthenium Tandem Catalysis, Org. Lett. 2018, 48, 194-197. 10.1021/acs.orglett.7b03556